SDS (TDR-WDA) SAFETY DATA SHEET TDR-WDA (AMAL-0640207-PDA-W) January 4, 2020 1. Company Identification Company 24 Hour Emergency Response Information Amalgamated Inc. CHEMTREC: 1-800-424-9300 6211 Discount Drive International: 1-703-527-3887 Fort Wayne, IN 46818 Amalgamated: 1-260-489-2549 Synonyms: POLISOBUTYLAMINE, POLYETHER AND HYDROCARBON 2. Hazards Identification 2.1. (GHS) Signal Word: DANGER GHS Hazard Pictograms: GH502 GH507 GH508 GH509 Hazard Statements (GHS) : H226 - Flammable Liquid and vapor. H304 - May be fatal if swallowed and enters airway. H315 - Cause skin irritation. H336 - may cause drowsiness or dizziness. H340 - May cause genetic defects. H350 - May cause cancer. H361 - Suspected of damaging fertility or the unborn child. H401 - Toxic to aquatic life. H411 - Toxic to aquatic life with long lasting effects. Precautionary Statements (GHS) : P201 - Obtain special instructions before use. P202 - Do not handle all safety precautions have been read and understood. P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, ventilating, and lighting equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge P261 - Avoid breathing vapors, mist, spray. P264 - Wash hands, forearms, and other exposed areas thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection, respiratory protection. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302+P352 - IF ON SKIN Wash with plenty of soap and water. P303+P361+P353 - If on skin(or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340 - IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing. P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a POISON CENTER/doctor/physician if you feel unwell. P321 - Specific treatment (see section 4) P331 - If swallowed do not induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362 - Take off contaminated clothing and wash before reuse. P370+378 - In case of fire: Use appropriate media for extinction. P391 - Collect spillage. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/containers to local, regional, national and international regulations. 2.2. Other Hazards Other Hazards Not Contributing to Classification: Exposure may aggravate those with the pre-existing eye, skin, or respiratory conditions. Exposure may aggravate individuals with pre-existing skin, kidney, liver, and pulmonary disorders. Flammable vapors can accumulate in head space of closed systems. 2.3. Unknown Acute Toxicity (GHS) No data available. 3. COMPOSITON / INFORMATION OF INGREDIENTS Ingredients: Mixture Chemical Name Percentage CAS# Solvent Naphtha, Light Aromatic 5.0 - 20.0 64742-95-6 2-Ethylhexyl Nitrate < 40.0 27247-96-7 Proprietary Polymer < 20 Trade Secret 1,2,4-Trimethylbenzene 5.0 - 10.0 95-63-6 1,3,5-Trimethylbenzene 3.0 - 6.0 108-67-8 Xylene 1.0 - 5.0 1330-20-7 Cumene 1.0 - 5.0 98-82-8 1,2,3-Trimethylbenzene 1.0 - 5.0 526-73-8 Dipropylene Glycol Methyl ether 1.0 - 10.0 3459-094-8 4. First -Aid Measures General advice: Immediately remove contaminated clothing. If inhaled: Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary. Immediate medical attention required. If on skin: Wash affected areas thoroughly with soap water. If irritation develops, seek medical attention. If in eyes: In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water, If irritation develops, seek medical attention. If swallowed: Rinse mouth and then drink plenty of water. Do not induce vomiting due to aspiration hazard. Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions. Immediate medical attention required. Note to Physician Treatment : Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Flash Point: approx. 46°C (114°F) Information on: Xylene Flash Point Method: PMCC ---------------------------------------- Suitable extinguishing media: Water spray Alcohol-resistant foam, dry powder, carbon dioxide. Unsuitable extinguishing media for safety reasons: Do Not spray heavy water stream. Use of heavy stream of water may spread fire. Hazards during fire-fighting: Harmful vapors: Evolution of fumes/fog. The substance/groups of substances mentioned can be released in case of fire. Protective equipment for fire- fighting: Firefighters should be equipped with self -contained breathing apparatus and turn-out gear. Other information: Do not allow run-off from fire-fighting to enter drains or water courses. 6. Accidental release measures General measures: Avoid static electric charges - Heat, sparks, flame Personal precautions: Use breathing apparatus if exposed to vapors/dust/aerosol. Do not get in eyes, on skin, or clothing. Take appropriate protective measures. Environmental precautions: Notify proper authorities. Do not discharge into drains/surface waters/groundwater. Substance/product is RCRA hazardous due to its properties. Cleanup: Spills should be contained, solidified, and placed in suitable containers for disposal. 7. Handling and Storage Handling: General advice: Keep away from sources of ignition - No smoking. Handle and open container with care. Keep container tightly sealed. Protection against fire and explosion: Vapors may form ignitable mixture with air. Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. Empty container tightly closed. Avoid all sources of ignition: heat, sparks, open flame. Storage: Keep container tightly closed. Avoid all sources of ignition: heat, sparks, open flame 8. Exposure Controls and Personal Protection Components Parameters: No occupational exposure limits(OELs) have been established for this product or its chemical components. Personal protective equipment Engineering controls: Emergency eye wash fountains and safety showers should be available in the Immediate vicinity of any potential exposure. Proper grounding procedures to avoid static electricity should be followed. Use explosion proof -equipment. Alarm detectors should be used when toxic gases may be released. Ensure all national /local regulations are observed Respiratory protection: Wear a NIOSH-certified (or equivalent) organic vapor/particulate respirator. Do not exceed the maximum use concentration for the respirator face piece/cartridge combination. For emergency or non-routine, high exposure situations, use a NIOSH-certified full face piece pressure demand self-contained breathing apparatus (SCBA) or a full face piece pressure demand supplied air respirator (SAR) with escape provisions. Materials for Protective Clothing Chemically resistant materials and fabrics. Wear fire/flame resistant/retardant clothing. Hand Protection Wear chemically resistant protective gloves. Eye Protection Chemical goggles or safety glasses. Skin and Body Protection Wear suitable protective clothing. Respiratory Protection Use NIOSH-approved air-purifying or supplied-air respirator where airborne concentrations of vapor or mist are expected to exceed exposure limits. Thermal Hazard Protection Wear suitable protective clothing Other Information When using, do not eat, drink or smoke Engineering controls: Emergency eye wash fountains and safety showers should be available in the Immediate vicinity of any potential exposure. Proper grounding procedures to avoid static electricity should be followed. Use explosion proof -equipment. Alarm detectors should be used when toxic gases may be released. Ensure all national /local regulations are observed. 9. Physical and Chemical Properties Form: liquid Odor: aromatic Color: dark amber Pour Point -10° F (MAX)Density: 0.9254 (15° C) Viscosity: 17.6147 (40° C) Solubility in water: insoluble Other information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Reactivity: Hazardous reactions will not occur under normal conditions. Conditions to avoid: Direct sunlight. Extreme high or low temperatures. Open flame. Incompatible materials. Heat sparks. Stability: May form flammable/explosive vapor-air mixture. Flammable liquid and vapor. Incompatible products: Strong acids. Strong bases. Strong oxidizers. Hazardous Decomposition Products: Carbon oxides (CO, CO2). May release flammable gases. Possibility of Hazardous reactions: Hazardous polymerization will not occur. 11. Toxicological information Acute toxicity: Not classified. Naphtha, petroleum, heavy catalytic reformed LD50 Dermal Rabbit > 2,000 mg/kg LC50 Inhalation Rat(mg/l) > 5.04 mg/l/4h Skin corrosion/Irritation: Causes skin irritation. Serious eye damage/Irritation: Not classified. Respiratory or skin Sensitization: Not classified. Germ Cell Mutagenicity: May cause genetic defects. Carcinogenicity: May cause cancer. Reproductive Toxicity: Suspected of damaging fertility or the unborn child. Specific target organ toxicity (single exposure): May cause drowsiness or dizziness. Specific target organ toxicity (Repeated exposure): Not classified. Aspiration hazard: May be fatal if swallowed and enters airway. Potential adverse human health effects and symptoms: Harmful if inhaled. Symptoms/injuries after inhalation: May cause drowsiness or dizziness. Respiratory tract irritation. Symptoms/injuries after skin contact: Causes skin irritation. Symptoms/injuries after eye contact: May cause for eye irritation Symptoms/injuries after ingestion: May be fatal if swallowed and enters airways. Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: Prolonged exposure may cause effects in specific organs such as the liver, kidneys, blood, and nervous system. Suspected of damaging fertility. Suspected of damaging the unborn child. May cause heritable genetic damage. May cause cancer. 12. Ecological Information Toxicity General : Toxic to aquatic life with long lasting effects EC50 other aquatic organisms 1 - 11mg/l (Exposure time: 72hr - Species: Pseudokirchneriella subcapitata) Degradability / Persistence: Aromatic solvent - may cause long term adverse effects in the environment. Biological / A biological Degradation: Aromatic solvent - Avoid release to the environment. Distillate fuels are potentially toxic to freshwater and saltwater ecosystems. Distillate fuels will normally float on water. In stagnant or slow-flowing waterways, a hydrocarbon layer can cover a large surface area. As a result, this oil layer can limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway can cause a fish kill or create an anaerobic environment. Also, this coating action can also kill plankton, algae and water birds. 13. Disposal considerations Waste disposal of substance: Dispose of in accordance with national, state and local regulations. Additional information: Handle empty containers with care because residual vapors are flammable. Ecology - Waste Materials: This material is hazardous to the aquatic environment. Keep out of sewers and waterways. 14. Transport Information Land transport USDOT Proper Shipping Name Environmentally hazardous substances, liquid, N.O.S. Hazard Class: 9 ID number: UN 3082 Label Code: 3 Packing Group III Marine Pollutant Marine pollutant ERG Number 128 Sea transport IMDG Proper Shipping Name Environmentally hazardous substances, liquid, N.O.S. Hazard Class: 9 ID number: UN 3082 Label Code: 3 Packing Group III EmS-No.(Fire) F-E EmS-No. (Spillage) S-E Marine Pollutant Marine pollutant Air Transport IATA/ICAO Proper Shipping Name Environmentally hazardous substances, liquid, N.O.S. Hazard Class: 9 ID number: UN 3082 Label Code: 3 Packing Group III ERG Code (IATA) 3L 15. Regulatory Information This material components are listed on the inventory of Existing Chemical Substances under the Toxic Substances under the Toxic Substances Control Act (TSCA). Canadian Disclosure List 1,2,4-TRIMETHYLBENZENE (95-63-6) 1,3,5- TRIMETHYLBENZENE (108-67-8) CUMENE (98-82-8) 1,2,3-TRIMETHYLBENZENE (526-73-8) AROMATIC SOLVENT (64741-69-0) SARA Title III - Section 313 1,2,4-TRIMETHYLBENZENE (95-63-6) XYLENE (1330-20-7) CUMENE (98-82-8) CERCLA Hazardous Substances XYLENE (1330-20-7) -RQ 1000lb CUMENE (98-82-8) RQ 5000lb RCRA Hazardous Substances XYLENE (1330-20-7) -- RCRA Code: U239 CUMENE (98-82-8) --RCRA Code: U055 Title V 1,2,4-TRIMETHYLBENZENE (95-63-6) XYLENE (1330-20-7) CUMENE (98-82-8) SC Toxic Air Pollutants List XYLENE (1330-20-7) CUMENE (98-82-8) This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under Proposition 65: Ethyl benzene, Naphthalene, Toluene, Benzene. 16. Other information This document has been prepared according with the SDS requirements of OSHA Hazard Communication Standard 29 CFR 1910.1200. SDS Prepared by: Amalgamated Inc. www.amalgamatedinc.com SDS Prepared on: 2020/1/4 AMAL-0640207-PDA-W is registered with the EPA IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OR ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNES, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNES PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FUTHRER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY AMALGAMATED, INC. HEREUNDER ARE GIVEN GRATIS AND AMALGAMATED, INC. ASSUMES NO OBLIGITATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMALTION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK”.